Synthesis, characterisation and methyl orange adsorption. Adsorption properties of methyl orange in water by sheep manure. Adsorption of methyl orange dye using femn composite powder as adsorbent. Biosorption conditions of methyl orange by humicola fuscoatra 1077 higher ph led to lower adsorption because of characteristics of biomass and methyl orange, which can also be seen in many other dyes and most of the researchers claimed that an acidic ph condition of dye solution was more effective for dye removal10,14,15. The purpose was to provide a new adsorption material for the treatment of methyl orange wastewater, and to provide a scientific basis for the new resource utilization method of sheep manure. Adsorption of methyl orange onto chitosan from aqueous solution article pdf available in journal of water resource and protection 210. Generally, the ph of the adsorption depends on the zero point charge of the methyl orange phzpc and the charge of the adsorbent surface. Adsorption behavior of methyl orange onto an aluminumbased. The adsorption of methyl orange onto vermiculite and ctmabvermiculite was studied at different ph levels, varying from 3 to 11 fig. Adsorption of methylene blue on cellulose from its own. No matter how many components are present in the system, the adsorption equilibria of pure components are the essential ingredient for the understanding of how much those components can be accommodated by a solid adsorbent duong, 1998. Batch adsorption experiments were carried out as a function of ph, contact time, adsorbate concentration, adsorbent dosage and temperature. Determination of biosorption conditions of methyl orange by. Department of civil engineering national institute of technology agartala agartala, india.
The adsorption behaviour of the cationic dye, methylene blue mb from its own solution and from its mixture with an anionic dye, methyl orange mo on cellulose has been investigated. This paper presents the feasibility for the removal of methyl orange mo dye from aqueous solution using an activated carbon prepared from prosopis juliflora bark. The adsorption of methyl orange mo from aqueous solutions on protonated crosslinked chitosan was studied in a batch system. Benefit of hydrophilicity for adsorption of methyl orange and. The chemical structure and properties of methyl orange are recorded in table 1. Kinetics studies on the adsorption of methyl orange and. Aqueous solutions were prepared using distilled water.
The adsorption behavior of an azo dye methyl orange mo on aluminum oxide nano particles anp generated by sol gel method has been performed to understand the physicochemical process involved and to explore the potential use of nano particles in textile effluent treatment and management. Adsorption isotherms, methyl orange, kinetic models, activated carbon an adsorption process. Adsorption of methyl orange dye using femn composite powder. Pdf equilibrium and kinetic adsorption studies of methyl. The kinetics and adsorption mechanism of methyl orange mo onto chitosan 10b were studied in the present work. The addition of ptfe to ac significantly decreased the hydrophilicity, which in turn, decreased both the amount of mo adsorbed and the regeneration efficiency. Batch adsorption experiments were carried out utilizing the composite films to adsorb a typical azo dye, i. Kinetic studies and equilibrium isotherm analyses for the.
The optimum dosage for both the systems was found to be 0. Adsorptive removal of methyl orange and methylene blue from. Modeling of experimental data for the adsorption of methyl. Our original solvothermal method to obtain magnetic iron oxidecarbon nanocomposites, uses 1,2propanediol as solvent, koh as precipitant and activated carbon, with a specific surface area of 890 m 2 g.
Removal of methyl orange from aqueous solutions by magnetic. Activated carbon derived from finger citron residue fac was tested as a new type of adsorbent for the removal of harmful dyes, namely, the anionic dye methyl orange mo and the cationic dye methylene blue mb, from contaminated water. In a wastewater resulted from the dyes finishing industry there are amounts of dyes very common methyl orange and heavy metals resulted mainly from the organometallic dyes. Adsorption of methyl orange onto protonated crosslinked chitosan. Adsorption of methyl orange dye using femn composite powder as adsorbent akash deb department of civil engineering national institute of technology agartala agartala, india abstract in this study femn composite powder was synthesized and used as an adsorbent for the removal of methyl orange mo from aqueous solution. The effects of ph, biochar dosage, adsorption time, temperature on adsorption of methyl orange mo in water by sheep manure biochar. Jun 29, 2012 the results showed that the surface area and micropores volume of activated carbon at the experimental conditions are achieved to 587 and 0. The parameters affecting the adsorption of methyl orange mo dye by ahm such as ph, adsorbent. Kinetic study of methyl orange adsorption on activated carbon. Removal of methyl orange mo from water by adsorption onto.
The purpose was to provide a new adsorption material for the treatment of methyl orange wastewater, and to provide a scientific basis. Nov 15, 2019 results showed that on increasing adsorbent dosage from 0. This study utilized swietenia mahagoni barka wood processing industry waste, for the preparation of activated carbon, and then investigated for the removal of methyl orange mo dye by the swietenia mahagoni bark activated carbon smbac. The parameters affecting the adsorption of methyl orange mo dye by ahm such as ph, adsorbent dosage, contact time, initial. The equilibrium data on the methyl orange fitted to both langmuir and. Abstract in this study femn composite powder was synthesized and used as an adsorbent for the removal of methyl orange mo from aqueous solution. The adsorption of methyl orange mo from aqueous solutions onto a kohactivated polypyrrolebased adsorbent pack was investigated using batch and fixedbed column techniques.
The adsorption behavior and mechanism of aminocrosslinked hypromellose ahm adsorbent crosslinked with epichlorohydrin and modified with diethylenetriamine were studied. Equilibrium and kinetic adsorption studies of methyl orange. Methyl orange mo and ethyl orange eo were selected as models of dye molecules. Results showed that on increasing adsorbent dosage from 0. Integration of adsorption and photocatalytic degradation of methyl orange using tio 2 ass nanocomposite the experiments were carried out in two consecutive conditions. Batch experiments were conducted to study the effect of reaction parameters on the adsorption of the dye such as. The adsorption of methyl orange mo from aqueous solutions onto a kohactivated polypyrrolebased adsorbent pack was investigated using batch and. Freundlich model best indicating heterogeneity of the surface of the clay sample.
Application of response surface methodology for optimization. Eo has only two methylenes more than mo, which makes it facile to analyze the effect of ph and ionic strength on the competitive adsorption of these dyes. Batch experiments showed that both the initial dye concentration and the ph of aqueous solutions significantly affect the adsorption capacity of dye mo on the chitosan 10b. Pdf chitosan was utilized as adsorbent to remove methyl orange mo from aqueous solution by adsorption. G, showed that the adsorption is endothermic, random and nonspontaneous at high temperature. Adsorption of methylorange from aqueous solution onto. Kinetic study of methyl orange adsorption on activated carbon derived from pine pinus strobus sawdust, biores. Various conditions were evaluated, including initial. Single and simultaneous adsorption of methyl orange and. Kinetic studies and equilibrium isotherm analyses for the adsorption of methyl orange by coal fly ash from aqueous solution. Removal of methyl orange by activated carbon modified by.
Modeling of experimental data for the adsorption of methyl orange from aqueous solution using a low cost activated carbon prepared from prosopis juliflora. Adsorption of azo dye methyl orange from aqueous solutions. Abstract in this work, the removal of methyl orange. Single and simultaneous adsorption of methyl orange and phenol onto magnetic iron oxidecarbon nanocomposites roxana istratiea, marcela stoiaa,b, cornelia pa. Adsorption of methyl orange onto chitosan from aqueous solution. Comparative study of the adsorption of methyl orange by bentonite.
Competitive adsorption of methyl orange and ethyl orange by. Adsorption of methyl orange from aqueous solution on anion exchange membranes. Preparation and characterization of activated carbon from date pits by chemical activation with zinc chloride for methyl orange adsorption khaled mahmoudi, noureddine hamdi, ezzeddine srasra laboratory of physicochemical of minerals materials and its applications national centre of research in materials sciences cnrsm b. The results indicate that fb adsorbs mo efficiently and could be utilized as a lowcost alternative adsorbent for the removal of anionic dyes in wastewater treatment.
The adsorption behavior of methyl orange dye from aqueous solution onto activated lignin was investigated as a function of equilibrium time, ph and concentration. Batch experiments were conducted to study the effects of ph, initial concentration of adsorbate and temperature on dye adsorption. Pdf modeling of experimental data for the adsorption of. Methyl orange mo was purchased from fluka chemika supplier company. Adsorption behavior and kinetics of methyl orange in water on. Removal of methyl orange from aqueous solution via adsorption. Simultaneous adsorption of methyl orange and heavy metals. The adsorption of methyl orange mo from aqueous solutions onto a kohactivated polypyrrolebased adsorbent pack was. Adsorption and photocatalysis for methyl orange and cd. The effects of adsorbent dosage, solution ph, coexisting anions, and temperature were studied.
Adsorption of methyl orange dye using femn composite. Adsorption, methylene blue, methyl orange, indigocarmine. Mo dye by adsorption on silver nanoparticles agnps coated activated carbon ac has. The adsorption behavior of methyl orange aqueous solution was investigated on huskbased activated carbon. Notably, it is a referred, highly indexed, online international journal with high impact factor. The parameters affecting the adsorption process such as. Adsorption of methyl orange onto chitosan from aqueous. Pdf adsorption of methyl orange onto chitosan from aqueous. Sep 11, 2018 activated carbon acpolytetrafluoroethylene ptfe electrodes were prepared and applied for methyl orange mo adsorption and electrofenton regeneration.
The structural, thermal, and morphological properties of the pack, analyzed by various methods. This material is unprecedented, and the modification method used to obtain it is relatively simple. The effects of temperature and kcl on the adsorption. Batch adsorption experiments were carried out as a function of ph, contact time, adsorbate concentration, adsorbent dosage and. Investigation of methyl orange adsorption from water using. Liquidphase adsorption experiments were conducted, and the maximum adsorption capacity was determined.
The structural, thermal, and morphological properties of the pack, analyzed by various methods, support its applicability as an adsorbent. Batch experiments were conducted to study the effects of ph, initial concentration of adsorbate. In this case the uptake of mo increased with decrease in temperature indicating that adsorption of methyl orange onto the clay is favoured by lower temperatures and also that the adsorption process was exothermic 24. However, due to the ionic nature of methyl orange, the retention of the dye by ionexchange processes3,src, particularly on clay surfaces, and adsorption at mineral surfaces such as geothite4,src, may lead to increased adsorption on some sediment and particulate surfacessrc.
The adsorptive removal of methyl orange dye using a sugar beet bagasse sbb as agroindustrial byproduct has been investigated. Mondal, zilu yao, liang ge and tongwen xu cas key laboratory of soft matter chemistry, lab of functional membranes, school of chemistry and material science, university of science and. Kurupstudies on the adsorption kinetics and isotherms for the removal and recovery of methyl orange from wastewaters using waste materials j. Introduction time is crucial to the success of most chemical processes. Chitosan was utilized as adsorbent to remove methyl orange mo from aqueous solution by adsorption. Effect of time on the adsorption of methylene blue, methyl. The powders obtained at 195 c were all magnetic, with no phase separation under the action of a magnet, suggesting the formation of a. Keywords adsorption, methyl orange, lobatse clay, kinetics, thermodynamics. Adsorption kinetics and equilibrium muhammad imran khan, liang wu, abhishek n. The adsorption potential of sbb was improved by grafting with fecl3. Original research adsorption properties of methyl orange in. Thermodynamics and adsorption study of methyl orange onto. Adsorption of methyl orange onto protonated crosslinked.
The results showed that the surface area and micropores volume of activated carbon at the experimental conditions are achieved to 587 and 0. In this study, efficiency of kaolinite kao, metakaolinite mk and activated geopolymer geo7 as adsorbents for the removal of methyl orange mo in aqueous solution were investigated. The effect of ph 310, adsorbent dose gl, initial mo dye concentration 10100 mgl. Enhanced adsorption of methyl orange by vermiculite. Adsorption of methyl orange using activated carbon prepared. Single and binary adsorption of sulfonamide antibiotics onto ironmodified clay. Pdf this paper present the efficiency of animal activated carbon in removal of methyl orange mo from aqueous solutions by adsorption. Thermodynamics and adsorption study of methyl orange. Abstractin this study, the cork powder was used as adsorbent to remove methyl orange mo from aqueous solutions by adsorption. The adsorption of methyl orange dye on activated carbon and bentonite type algerian clay from aqueous solutions was investigated. The data fit onto this model is good suggesting that the adsorption process onto the adsorbent is overall third order which implies that the rate determining step in the mechanism involves three bodies colliding at the same time for instance two methyl orange molecules and an adsorption site or one methyl orange molecule, a solvent molecule. Mar 11, 2020 the adsorption behavior and mechanism of aminocrosslinked hypromellose ahm adsorbent crosslinked with epichlorohydrin and modified with diethylenetriamine were studied.
The kinetic data obtained from different batch experiments were analyzed using. Notably, it is a referred, highly indexed, online international journal with. Characterization of aminocrosslinked hypromellose and its. Activated carbon acpolytetrafluoroethylene ptfe electrodes were prepared and applied for methyl orange mo adsorption and electrofenton regeneration. An adsorption kinetic study revealed a preferably pseudosecondorder r2 0.
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